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Volume :32 Issue : 1 2005      Add To Cart                                                                    Download

Synthesis and spectral studies on Chromium(III) and Manganese(II) complexes with three new macrocyclic ligands

Auther : DEEPAK SHUKLA*, SULEKH CHANDRA1, REENA TYAGI2 AND MUKESH KUMAR3

 *34, Shanti Kunj, Bhatwara, Sardhana, Meerut – 250342 (U.P.) India, deepak_shuk78@rediff.com
1Department of Chemistry, Zakir Husain College, University of Delhi, J. L. Nehru Marg, New Delhi – 110002, INDIA.

2Department of Chemistry, Sanjay Gandhi Post Graduate College, Sarurpur Khurd,C.C.S. University, Meerut (U.P.) INDIA

3 Department of Chemistry, D.A.V. (P.G.) College, Dehradun – 248 001, Uttaranchal,INDIA*Corresponding Author

ABSTRACT

 Complexes of Cr(III) and Mn(II) containing a tetradentate macrocyclic nitrogen donor ligand have been prepared via template reaction of 2,3-pentanedione, o-phenylenediamine/1,2-diaminopropane/m-phenylenediamine and metal ions. The complexes have been characterized on the basis of elemental analyses, molar conductance measurements, magnetic susceptibility measurements, infrared, electronic and electron spin resonance spectral studies. All of complexes were found to have six-coordinate geometry and high-spin electronic configuration.

 Key words:  Chromium(III), Manganese(II) complexes; synthesis and spectral studies

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